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金属表面硅烷处理技术

朱丹青 , Wim J.van Ooij , 王一建 , 陆国建 , 沈泉飞 , 支波

电镀与涂饰

根据金属腐蚀及涂层防腐原理,研究了金属表面硅烷处理工艺技术及处理后的功能特性,分别进行了中性盐雾、铜加速醋酸盐雾、电偶腐蚀.大气暴露和海水浸泡试验.结果表明,金属表面硅烷处理工艺技术可以取代涂装前磷化及铬化处理.该技术具有常温处理、无毒性无污染的特点,可广泛应用于涂装前处理与防腐领域.

关键词: 硅烷 , 防腐 , 盐雾试验 , 电偶腐蚀 , 大气暴露 , 海水浸泡 , 涂装

Simple approach to estimating the van der Waals interaction between carbon nanotubes

Physical Review B

The van der Waals (vdW) interactions between carbon nanotubes (CNTs) were studied based on the continuum Lennard-Jones model. It was found that all the vdW potentials between two arbitrary CNTs fall on the same curve when plotted in terms of certain reduced parameters, the well depth, and the equilibrium vdW gap. Based on this observation, an approximate approach is developed to obtain the vdW potential between two CNTs without time-consuming computations. The vdW potential estimated by this approach is close to that obtained from complex integrations. Therefore, the developed approach can greatly simplify the calculation of vdW interactions between CNTs.

关键词: molecules;clusters;bundles;growth;phase;c-60

Van der Waals interactions between two parallel infinitely long single-walled nanotubes

Chemical Physics Letters

The potential energies of van der Waals (VDW) interactions between two parallel, infinitely long and perfect SWNTs with identical, and different sizes were studied based on the continuum Lennard-Jones model. The conclusion of Girifalco's work on (n, n) SWNTs that the potentials of SWNT-SWNT fell on a single curve, is also applicable to SWNTs with different sizes. We further obtained the corresponding constants of the well depth \phi(0)\ and equilibrium VDW gap g(0) for SWNTs with a radius from 2 to 25 Angstrom. (C) 2005 Elsevier B.V. All rights reserved.

关键词: carbon nanotubes;graphite;bundles;c-60;moduli;ropes

Purification of multiwalled carbon nanotubes by annealing and extraction based on the difference in van der Waals potential

Journal of Physical Chemistry B

The potential energies of van der Waals interactions between two multiwalled carbon nanotubes (MWNTs) as well as two carbon nanoparticles (CNPs) were calculated and compared on the basis of the continuum Lennard-Jones model. The well depth of the potential is 1 order of magnitude higher for MWNTs than for CNPs, indicating that MWNTs and CNPs can be separated from each other through polymer-induced steric stabilization. On the basis of this prediction, a novel method for the purification of MWNTs was proposed. The method involves a high-temperature annealing ( 2600 degrees C, 1 h) followed by an extraction treatment with a selected dispersing agent. While the annealing process evaporates the metal particles, the extraction treatment removes CNPs. The quality of the nanotubes obtained after purification was examined by laser Raman, thermogravimetric analysis, and electron microscopy observations.

关键词: decomposition;hydrocarbons;temperature;nanofibers;pyrolysis;monoxide;bundles;purity;gas

Spin waves in a four-sublattice Heisenberg ferrimagnet or ferromagnet with different exchange constants (J(ab)=J(cd)not equal J(bc)=J(da))

Physical Review B

The Hamiltonian for a four-sublattice Heisenberg ferrimagnet or ferromagnet with different exchange constants (J(ab) = J(cd) not equal J(bc) = J(da)) was established. An extended Bogoliubov transformation was developed by solving an equation group, consisting of 20 equations and 20 unknowns. The procedure for solving the equation group was carried out by introducing a simple way of reducing the numbers of the equations and the unknowns. The spin-wave spectra in the present system have been determined by performing the standard Holstein-Primakoff transformation and the Bogoliubov one. It has been found that the spin-wave spectra of the present system depend on the exchange constants and that the degeneracy of the spin-wave spectra remains. The results for a special case (J(ab) = J(bc)) i.e., an antiferromagnet are discussed briefly. The spin-wave spectra of the four-sublattice Heisenberg antiferromagnet are found to be degenerative also and they are linear in k for small k.

关键词: model

高分子专利j

高分子材料科学与工程

专利名称:具有改进的抗冲击性、尺寸稳定性和吹塑成形性能的热塑性ABS树脂组合物专利申请号:CN200580040787.3公开号:CN101065413申请日:2005.03.31公开日:2007.10.31申请人j韩国第一毛织株式会社根据本发明的热塑性ABS树脂组合物包括:(a)2

关键词: 专利名称 , 高分子 , 树脂组合物 , 专利申请号 , 尺寸稳定性 , 抗冲击性 , 株式会社 , 成形性能

Van Hove奇异性、非电声作用与HgBa2Cun-1CunO2n+2+δ(n=1,2,3)系统的超导电性

张霞 , 苏希玉 , 侯芹英 , 侯艳丽

低温物理学报 doi:10.3969/j.issn.1000-3258.2008.03.011

考虑态密度的Van Hove奇异性和非电声作用,我们在BCS理论框架内研究了HgBa2Cun-1CunO2n+2+δ(n=1,2,3)系统的超导转变温度和同位素效应.结果表明,当同时考虑Van Hove奇异性和非电声作用时,可以更好地解释HgBa2Cun-1CunO2n+2+δ(n=1,2,3)系统的超导性质.

关键词: Van Hove奇异性 , 非电声作用 , 超导转变温度 , 同位素效应

Study on the Relationship Between J-Integral and COD

Y.G. Cao , X.Y. Sun

金属学报(英文版)

J-integral and crack opening displacement δ(COD) were important parameters for characterization of fractures in engineering materials. The relationship between J-integral and COD has been investigated for a long time and was enerally represented as J = m σyδ, where σy is the yield strength and m is a function of specimen geometry and material properties. To determine the value of m, extensive studies and experiments have been performed. The method that used the fracture-surface topography analysis (FRASTA) for determining J-integral from fracture surfaces of materials was introduced. On the basis of the relationship between COD and fracture surface average profile, the relationship between J-integral and COD was deduced and compared with the generally used equation. The method was experimentally confirmed to be able to provide a new way to determine the relationship between J-integral and COD.

关键词: FRASTA , null , null

浅析CTOD和J积分的关系

周峰峦 , 郭震

物理测试 doi:10.13228/j.boyuan.issn1001-0777.20160084

推导了CTOD和J积分的关系,并且从试验角度利用三点弯曲试样进行CTOD试验,根据ASTM E1820对GB/T 21143-2014中公式34进行了评价,研究表明,在小屈服范围内,采用裂纹嘴张开位移可以同时得到CTOD和J积分,从而可以简化J积分的试验装置.

关键词: J积分 , CTOD , 小屈服

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